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Journal Articles

Evolved gases from organic materials used in the superconducting magnets irradiated by gamma rays at liquid nitrogen temperature

Idesaki, Akira; Morishita, Norio; Ito, Hisayoshi; Kamiya, Tomihiro; Nakamoto, Tatsushi*; Kimura, Nobuhiro*; Makida, Yasuhiro*; Ogitsu, Toru*; Ohata, Hirokatsu*; Yamamoto, Akira*

AIP Conference Proceedings 824, p.330 - 334, 2006/03

Polyimide films and glass fiber reinforced plastics (GFRPs) are used as insulating or structural materials for superconducting magnets in a neutrino beam line of the Japan Proton Accelerator Research Complex (J-PARC). It is indispensable to evaluate radiation resistance of these materials, because they are required to keep their electrical and mechanical properties in a high radiation field of 30 kGy/year at low temperature of 4 K. In this work, the gas evolution resulting from chemical reactions induced in the polyimide films and GFRPs by $$gamma$$ ray irradiation at 77 K was investigated. It was found that the main component of the evolved gas is hydrogen. The amount of hydrogen evolved from the superconducting magnet system used in the neutrino beam line was estimated to be 0.37 mol/year (0.01 L/year as the volume of liquid hydrogen). It indicates that the hydrogen evolved from the organic materials does not influence on the operation of the helium purifying system.

Journal Articles

Ion-beam-induced dual-tone imaging of polyimide via two step imidization

Suzuki, Yasuyuki; Maekawa, Yasunari; Yoshida, Masaru; Maeyama, Katsuya*; Yonezawa, Noriyuki*

Chemistry of Materials, 14(10), p.4186 - 4191, 2002/10

 Times Cited Count:17 Percentile:53.64(Chemistry, Physical)

Dual tone imaging of polyimide films was prepared by Xe ion beam irradiation of partially imidized polyamic acid (PAA) films followed by alkaline etching in aqueous tetramethylammonium hydroxide solution and heating of treated films. In 87% imidized PAA film, ion beam irradiation produced a negative hemispheric structured image with 1.0 mm height and 1.5 mm diameter. In contrast, a positive hole pattern with 0.3 mm diameter appeared on the 82% imidized PAA film. Positive and negative images were considered to be switched by slight change in the balance of scission and crosslinking of the polymer chains, resulting from energy deposition of the ion beam.

Journal Articles

A Steady-state simulation model of gas separation system by hollow-filament type membrane module

Iwai, Yasunori; Yamanishi, Toshihiko; Nishi, Masataka

Journal of Nuclear Science and Technology, 36(1), p.95 - 104, 1999/01

 Times Cited Count:12 Percentile:66.16(Nuclear Science & Technology)

no abstracts in English

JAEA Reports

Study on methane separation from steam reforming product gas with polyimide membrane

*; Inagaki, Yoshiyuki; ; Sekita, Kenji; Haga, Katsuhiro; Hino, Ryutaro

JAERI-Research 97-076, 33 Pages, 1997/10

JAERI-Research-97-076.pdf:1.3MB

no abstracts in English

Journal Articles

Radiation resistant organic materials

Seguchi, Tadao

Hoshasen To Sangyo, 0(66), p.4 - 8, 1995/00

no abstracts in English

Journal Articles

Elution of residual ions with etching of heavy ion-injected polyimide

Komaki, Yoshihide; ; Sakurai, Tsutomu; Matsumoto, Yasuyo*

Radiat. Meas., 23(4), p.725 - 729, 1994/00

 Times Cited Count:0 Percentile:0.01(Nuclear Science & Technology)

no abstracts in English

JAEA Reports

Outgas and vacuum seal characteristics of irradiated polyimide O-ring

*; Shibanuma, Kiyoshi; Okawa, Yoshinao; Seguchi, Tadao

JAERI-M 93-067, 43 Pages, 1993/03

JAERI-M-93-067.pdf:1.5MB

no abstracts in English

Journal Articles

Radiation effect of aromatic thermoplastic polyimide(new TPI)

*; Hama, Yoshimasa*; Sasuga, Tsuneo; Seguchi, Tadao

Polymer, 32(14), p.2499 - 2504, 1991/00

 Times Cited Count:19 Percentile:67.41(Polymer Science)

no abstracts in English

JAEA Reports

Helium gas permeability of KAPTON polyimide film

*; Konishi, Hiroyuki; Nagasaki, Takanori

JAERI-M 90-137, 11 Pages, 1990/08

JAERI-M-90-137.pdf:0.47MB

no abstracts in English

Journal Articles

Heavy ion track microfilter of polyimide film

Komaki, Yoshihide; Matsumoto, Yasuyo*; ; Sakurai, Tsutomu

Polym. Commun., 30, p.43 - 44, 1989/02

no abstracts in English

Journal Articles

Oxidative irradiation effects on several aromatic polyimides

Sasuga, Tsuneo

Polymer, 29, p.1562 - 1568, 1988/00

 Times Cited Count:11 Percentile:55.99(Polymer Science)

no abstracts in English

Journal Articles

Radiation effects of aromatic polyimide

Sasuga, Tsuneo; Hagiwara, Miyuki

Kobunshi Rombunshu, 42(4), p.283 - 290, 1985/04

 Times Cited Count:2 Percentile:22.32(Polymer Science)

no abstracts in English

Journal Articles

Irradiation effects on the mechanical properties of composite organic insulators

; M.A.Kirk*; R.C.Birtcher*; Hagiwara, Miyuki; Kawanishi, Shuichi

Nuclear Instruments and Methods in Physics Research B, B1, p.610 - 616, 1984/00

no abstracts in English

Journal Articles

Mechanical properties of organic composite materials irradiated with 2MeV electrons

; M.A.Kirk*; R.C.Birtcher*; Hagiwara, Miyuki; Kawanishi, Shuichi

Journal of Nuclear Materials, 119(2-3), p.146 - 153, 1983/00

 Times Cited Count:15 Percentile:81.67(Materials Science, Multidisciplinary)

no abstracts in English

Oral presentation

LET dependence on the track etch rate in ion irradiated polyimide films

Koshikawa, Hiroshi; Asano, Masaharu*; Yamaki, Tetsuya; Maekawa, Yasunari

no journal, , 

We investigated track etch rates (V$$_{T}$$) of polyimide irradiated with different ions by a conductivity technique and their LET dependence. Both of 12 and 25 $$mu$$m thick films were irradiated with 450 MeV $$^{129}$$Xe, 250 MeV $$^{40}$$Ar and 75 MeV $$^{20}$$Ne and then were etched with a sodium hypochlorite solution. The conductometric analysis involves recording electric conductance of the etchant across the film during the etching time. When the etched pores from both sides of the film made contact with each other, the conductance suddenly increased to find the breakthrough time (T$$_{B}$$). A V$$_{T}$$ value was obtained by dividing the half thickness of the films by T$$_{B}$$. The Xe ions with the highest LET of 12 MeV/$$mu$$m gave ca. 20 times higher V$$_{T}$$ than the Ne ions. The change in V$$_{T}$$ for the different beams is ascribed to an LET effect by considering that the bombardment with high-LET ions produces more severe molecular damage in each track.

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